Please use this identifier to cite or link to this item: http://dspace.cus.ac.in/jspui/handle/1/6354
Full metadata record
DC FieldValueLanguage
dc.contributor.authorAdhikary, Amit-
dc.contributor.authorAkhtar, Sohel-
dc.contributor.authorPariyar, Anand-
dc.contributor.authorBatsanov, Andrei S.-
dc.contributor.authorMondal, Raju-
dc.date.accessioned2019-09-24T06:54:16Z-
dc.date.available2019-09-24T06:54:16Z-
dc.date.issued2019-
dc.identifier.citationACS Omega V.4 (5), 2019, 8731-8738 pp.en_US
dc.identifier.urihttps://doi.org/10.1021/acsomega.8b03400-
dc.identifier.urihttp://dspace.cus.ac.in/jspui/handle/1/6354-
dc.description.abstractThe present article deals with an one-to-one structure−property correspondence of a dinuclear iron complex, [Dipic(H2O)- FeOH]2·H2O (1) (Dipic = pyridine-2,6-dicarboxylic acid). Variabletemperature X-ray single-crystal structural analysis confirms a phase transition of complex 1 to complex 2 ([Dipic(H2O)FeOH]2) at 120°C. Further, single-crystal-to-single-crystal (SCSC) transformation was monitored by temperature-dependent single crystal X-ray diffraction, powder X-ray diffraction, time-dependent Fourier-transform infrared spectroscopy, and differential scanning calorimetry. SCSC transformation brings the change in space group of single crystal. Complex 1 crystallizes in the C2/c space group, whereas complex 2 crystallizes in the Pi̅space group. SCSC transformation brings the change in packing diagram as well. Complex 1 shows two-dimensional network through H-bonding, whereas the packing diagram of complex 2 shows a zigzag-like arrangement. Phase transformation not only fetches structural changes but also in the magnetic properties. Difference in Fe−O−Fe bond angles of two complexes creates notable variation in their antiferromagnetic interactions with adjacent metal centers.en_US
dc.language.isoenen_US
dc.publisherACS Publicationsen_US
dc.titleTemperature-Induced single-crystal-to-single-crystal transformations with consequential changes in the magnetic properties of Fe(III) complexesen_US
dc.typeArticleen_US
dc.identifier.Volume4-
dc.identifier.Issue5-
dc.identifier.eissn2470-1343-
Appears in Collections:Anand Pariyar

Files in This Item:
File Description SizeFormat 
acsomega.8b03400.pdf4.49 MBAdobe PDFView/Open


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.