000			00359nam a2200133Ia 4500
999			_c186373 _d186373
020			_a9783527335947
040			_cCUS
082			_a547.2 _bSIN/R
100			_aSingh, Maya Shankar.
245		0	_aReactive Intermediates in organic chemistry: structure, mechanism, and reactions/ _cMaya Shankar Singh
260			_aWeinheim: _bWiley-VCH, _c2014.
300			_ax, 283 p. : _bill. ; _c25 cm.
505			_aPreface 1 Introduction Reaction Mechanism and Reaction Arrows Properties and Characteristics of a Reaction Summary 2 Carbocations Introduction History Sturctures and Geometry of Carbocations Generation of Carbocation Carbocation Stability Detection of Carbocations Fate of Carbocations Nonclassical Carbocations Radical Cations Summary 3 carbanions Structure and Geometry of Carbanions Generation of Carbanions Stability of Carbanions Reactions of Carbanions Enolate Reactions with Carbonyl Groups Rearrangements of Carbanions Chiral Carbanions Carbanions and Tautomerism Summary 4 Radicals Introduction Detection and Characterization of Radicals Structure and Bonding of Radicals Generation of Free Radicals Stability of Radicals Reactions of Free Radicals Stereochemistry of Radical Reactions Biradicals Summary 5 Carbenes Structure and Geometry of Carbenes Generation of Carbenes Reactions of Carbenes Carbenes and Carbene Ligands in Organometallic Chemistry Summary 6 Niternes ntroduction Structure and Reactivity Generation of Nitrenes Reactions of Nitrenes Summary 7 Miscellaneous intermediates Arynes Ketenes and Cumulenes ortho-Quinone Methides Zwitterions and Dipoles Antiaromatic Systems Tetrahedral Intermediates Summary Index
650			_aIntermediates (Chemistry)
650			_aPhysical organic chemistry
650			_aChemical reactions
942			_cWB16