000 00359nam a2200145Ia 4500
999 _c185160
_d185160
020 _a9780199663347
040 _cCUS
082 _a547.0076
_bCLA/S
100 _aClayden, Jonathan
245 0 _aSolutions Manual to accompany/
_cJonathan Clayden, Nick Greeves, Stuart Warren
250 _a2nd. ed.
260 _aUK :
_bOUP,
_c2001.
300 _a517p. :
_bill.(some col.) ;
_c25cm.
505 _a1 What is organic chemistry?; Organic chemistry and you; Organic compounds; Organic chemistry and industry; Organic chemistry and the periodic table; Organic chemistry and this book; Further reading; 2 Organic structures; Hydrocarbon frameworks and functional groups; Drawing molecules; Hydrocarbon frameworks; Functional groups; Carbon atoms carrying functional groups can be classified by oxidation level; Naming compounds; What do chemists really call compounds?; How should you name compounds? Further reading 3 Determining organic structures; Introduction; Mass spectrometry; Mass spectrometry detects isotopes; Atomic composition can be determined by high-resolution mass spectrometry; Nuclear magnetic resonance; Regions of the [sup(13)]C NMR spectrum; Different ways of describing chemical shift; A guided tour of the [sup(13)]C NMR spectra of some simple molecules; The [sup(1)]H NMR spectrum; Infrared spectra; Mass spectra, NMR, and IR combined make quick identification possible; Double bond equivalents help in the search for a structure; Looking forward to Chapters 13 and 18. Further reading 4 Structure of molecules; Introduction; Electrons occupy atomic orbitals; Molecular orbitals-diatomic molecules; Bonds between different atoms; Hybridization of atomic orbitals; Rotation and rigidity; Conclusion; Looking forward; Further reading; 5 Organic reactions; Chemical reactions; Nucleophiles and electrophiles; Curly arrows represent reaction mechanisms; Drawing your own mechanisms with curly arrows; Further reading; 6 Nucleophilic addition to the carbonyl group; Molecular orbitals explain the reactivity of the carbonyl group; Attack of cyanide on aldehydes and ketones. The angle of nucleophilic attack on aldehydes and ketonesNucleophilic attack by 'hydride' on aldehydes and ketones; Addition of organometallic reagents to aldehydes and ketones; Addition of water to aldehydes and ketones; Hemiacetals from reaction of alcohols with aldehydes and ketones; Ketones also form hemiacetals; Acid and base catalysis of hemiacetal and hydrate formation; Bisulfite addition compounds; Further reading; 7 Delocalization and conjugation; Introduction; The structure of ethene (ethylene, CH[sub(2)]=CH[sub(2)]); Molecules with more than one C=C double bond.
650 _aChemistry, Organic -- Textbooks.
650 _aChemistry, Organic.
650 _aSCIENCE -- Chemistry -- Organic.
700 _aGreeves, Nick
700 _aWarren, Stuart
942 _cWB16