000 01596cam a22003857a 4500
999 _c164227
_d164227
020 _a9783540495741 (hbk.)
020 _a3540495746 (hbk.)
040 _cCUS
082 0 4 _a539.9
_bTOY/L
100 1 _aToyota, Naoki.
245 1 0 _aLow-dimensional molecular metals/
_cNaoki Toyota, Michael Lang, Jens Müller.
260 _aBerlin :
_bSpringer,
_cc2007.
300 _axvii, 300 p. :
_bill. ;
_c24 cm.
504 _aIncludes bibliographical references (p. [249]-289) and index.
505 _a2 Basic Concepts .... ...... ..... .... .... 7 2.1 Charge Tansfer ......... 7 2.2 Molecular Orbitals and Transfer Integrals .............. 8 3 Structural Aspects . . . . . .................. . . , 13 3.1 Molecular Building Blocks ............13 3.2 Crystal Structures ................... ........ . 16 3.2.1 Quasi-One-Dimensional Compounds ............. 16 3.2.2 Quasi-Two-Dimensional Compounds ............. 19 3.2.3 Three-dimensional Compounds.. . ......... 25 3 3 Anion Ordering and Glassy Phenomena .............. 29 4 Normal-State Properties ..... ............. . 37 4.1 light-Binding Model .. ... .... ... ............ . 37 4.2 Fermi Surfaces and Low Dimensionality . ...... ....... 42 4 3 Electronic Properties ..... ............. . . 45 4.3.1 Transport and Optical Properties .... ....... . 45 4.3.2 Thermal and Magnetic Properties ............. . 63 4.4 Instabilities Involving Spin- and Charge-Degrees of Freedom 75 4.4.1 Charge- and Spin-Density-Waves ................. 75 4 4.2 Spin-Peierls State .................. ........ . 81 4 .43 Charge-Ordering Phenomena ................... 83 4.5 Many-Body Effects .................... 87 4.6 Phase Diagrams .... ....... ........... . 91 5 Magnetic-Field Effects .,,... ....... 99 5.1 Electron Motion in Magnetic Fields . ..... ... .. 100 5.1 1 Semi-Classical Description in k-Space .. ..... 100 5.1.2 Angular-Dependent Magnetoresistance Oscillations , 1.01 5 1.3 Magneto-Optic Resonances ... ......... . 106 5.2 Magnetic Quantum Oscillations ..... ..... ....... 109 5.2.1 Landau Levels and Lifshitz-Kosevich Theory ....... 109 5.2.2 Magnetic Breakdown and Quantum Interference...... 117 5.2.3 Two-Dimensionality EffectI .......... ... .... 120 5.2.4 Superconducting Vortex Stiaes. 123 S.2.5 Magnetic Exchange-Interaction 126 5.3 High-Magnetic Field States ..... ........ . ..... 128 5 3.1 Field-Induced Cascade Transitions to SDWs and Anomalous High-Field States . .......... 128 5.3.2 Field-Induced Destruction of CDW and Anomalous High-Field States .. .. ..... . 33 5.3.3 Approaching the Quantum Limit ..... ...........138 6 Superconductivity ....... ... .. .... .. .... . ... . . 141 6.1 Occurrence of Superconductivity in Molecular Metals ...... 141 6 2 Ginzburg-Landau Theory ............. ....... ... 143 6.3 The Superconducting Phase Transition ..... ..... ... 147 6.3.1 Anisotropy and Superconducting Fluctuations .......148 6.3.2 Pressure Dependence of T' . ............. . ... 153 6.3.3 Disorder ............. ................. . . . 157 6.4 Superconducting Parameters .. . . .. ..... . ... ... 164 6.4.1 (TM TSF)2X .. . . ....... ........... . 165 64.2 (BEDT-TTF)2X and (BEDT-TSF)2X ....1..... . 166 6.5 The Superconducting Mixed State . ...... ........ 170 6.5.1 Overview . ... .. . .. . .. . . . ..... . .... . 170 6.5.2 Basic Concepts of Vortex Matter in Quasi-Two-Dimensional Systems .. ...... 172 6.5.3 Experimental Findings for (BEDT-TTF)2X........ 175 6.6 Superconducting Order-Parameter ... ........ ..... ... 188 6.7 On the Pairing Mechanism .... .. .. .. .. .... . 210 7 Phenomena of Interacting Tr and d-Electrons .........219 7.1 (DCNQI)2Cu .. ............. ... .. .. . . . 219 7.1.1 Crystal Structure and Electrical Conductivity ........ 219 7.1.2 Reentrant Metal-Insulator Transition ......... . 221 7.2 (BEDT-TSF)2FeX4 (X=CI,Br) . . ........... ....... 224 7.2.1 Crystal Structures and Transfer Integrals ....... 225 7.2.2 Conductivity and Magnetism ............ . ..... 227 7.2.3 Magnetic Interactions and Mean-Field Theories .... 229 7.2 4 Anomalous Metallic States ............ . .. . .. 232 7.2 5 Antiferromagnetic Insulating States ..... ..... .... 236 7.2.6 Magnetic Field-Induced Transitions ........... 241
650 0 _aConducting polymers.
650 0 _aOne-dimensional conductors.
650 0 _aMolecular electronics.
700 1 _aLang, Michael,
700 1 _aMüller, Jens,
942 _cSC79