TY  - BOOK
AU  - Singh, Maya Shankar.
TI  - Reactive Intermediates in organic chemistry: structure, mechanism, and reactions
SN  - 9783527335947
U1  - 547.2 
PY  - 2014///
CY  - Weinheim
PB  - Wiley-VCH
KW  - Intermediates (Chemistry)	
KW  - Physical organic chemistry	
KW  - Chemical reactions	
N1  - Preface 

1 Introduction 

Reaction Mechanism and Reaction Arrows

Properties and Characteristics of a Reaction

Summary

2 Carbocations

Introduction

History

Sturctures and Geometry of Carbocations

Generation of Carbocation

Carbocation Stability

Detection of Carbocations 

Fate of Carbocations

Nonclassical Carbocations 

Radical Cations Summary

3 carbanions 

Structure and Geometry of Carbanions

Generation of Carbanions 

Stability of Carbanions 

Reactions of Carbanions 

Enolate Reactions with Carbonyl Groups 

Rearrangements of Carbanions

Chiral Carbanions

Carbanions and Tautomerism Summary

4 Radicals 

Introduction 

Detection and Characterization of Radicals 

Structure and Bonding of Radicals 

Generation of Free Radicals

Stability of Radicals

Reactions of Free Radicals 

Stereochemistry of Radical Reactions

Biradicals Summary 

5 Carbenes 

Structure and Geometry of Carbenes 

Generation of Carbenes

Reactions of Carbenes 

Carbenes and Carbene Ligands in Organometallic Chemistry 

Summary 

6 Niternes 

ntroduction

Structure and Reactivity 

Generation of Nitrenes 

Reactions of Nitrenes 

Summary

7 Miscellaneous intermediates

Arynes

Ketenes and Cumulenes

ortho-Quinone Methides

Zwitterions and Dipoles 

Antiaromatic Systems

Tetrahedral Intermediates

Summary 

Index

ER  -