Singh, Maya Shankar. <br/><br/>
Reactive Intermediates in organic chemistry: structure, mechanism, and reactions/ 
Maya Shankar Singh 
 - Weinheim:  Wiley-VCH,  2014. 
 - x, 283 p. :  ill. ;  25 cm. 
<br/><br/>Preface <br/><br/>1 Introduction <br/><br/>Reaction Mechanism and Reaction Arrows<br/><br/>Properties and Characteristics of a Reaction<br/><br/>Summary<br/><br/>2 Carbocations<br/><br/>Introduction<br/><br/>History<br/><br/>Sturctures and Geometry of Carbocations<br/><br/>Generation of Carbocation<br/><br/>Carbocation Stability<br/><br/>Detection of Carbocations <br/><br/>Fate of Carbocations<br/><br/>Nonclassical Carbocations <br/><br/>Radical Cations Summary<br/><br/>3 carbanions <br/><br/>Structure and Geometry of Carbanions<br/><br/>Generation of Carbanions <br/><br/>Stability of Carbanions <br/><br/>Reactions of Carbanions <br/><br/>Enolate Reactions with Carbonyl Groups <br/><br/>Rearrangements of Carbanions<br/><br/>Chiral Carbanions<br/><br/>Carbanions and Tautomerism Summary<br/><br/>4 Radicals <br/><br/>Introduction <br/><br/>Detection and Characterization of Radicals <br/><br/>Structure and Bonding of Radicals <br/><br/>Generation of Free Radicals<br/><br/>Stability of Radicals<br/><br/>Reactions of Free Radicals <br/><br/>Stereochemistry of Radical Reactions<br/><br/>Biradicals Summary <br/><br/>5 Carbenes <br/><br/>Structure and Geometry of Carbenes <br/><br/>Generation of Carbenes<br/><br/>Reactions of Carbenes <br/><br/>Carbenes and Carbene Ligands in Organometallic Chemistry <br/><br/>Summary <br/><br/>6 Niternes <br/><br/>ntroduction<br/><br/>Structure and Reactivity <br/><br/>Generation of Nitrenes <br/><br/>Reactions of Nitrenes <br/><br/>Summary<br/><br/>7 Miscellaneous intermediates<br/><br/>Arynes<br/><br/>Ketenes and Cumulenes<br/><br/>ortho-Quinone Methides<br/><br/>Zwitterions and Dipoles <br/><br/>Antiaromatic Systems<br/><br/>Tetrahedral Intermediates<br/><br/>Summary <br/><br/>Index<br/>  
<br/><br/><label>ISBN: </label>9783527335947 
<br/><br/><label>Subjects--Topical Terms: </label><br/>Intermediates (Chemistry)	<br/>Physical organic chemistry	<br/>Chemical reactions	
<br/><br/><label>Dewey Class. No.: </label>547.2  / SIN/R