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Reactive Intermediates in organic chemistry: structure, mechanism, and reactions/ Maya Shankar Singh

By: Singh, Maya ShankarMaterial type: Text

TextPublication details: Weinheim: Wiley-VCH, 2014Description: x, 283 p. : ill. ; 25 cmISBN: 9783527335947Subject(s): Intermediates (Chemistry) | Physical organic chemistry | Chemical reactions DDC classification: 547.2

Contents:

Preface 1 Introduction Reaction Mechanism and Reaction Arrows Properties and Characteristics of a Reaction Summary 2 Carbocations Introduction History Sturctures and Geometry of Carbocations Generation of Carbocation Carbocation Stability Detection of Carbocations Fate of Carbocations Nonclassical Carbocations Radical Cations Summary 3 carbanions Structure and Geometry of Carbanions Generation of Carbanions Stability of Carbanions Reactions of Carbanions Enolate Reactions with Carbonyl Groups Rearrangements of Carbanions Chiral Carbanions Carbanions and Tautomerism Summary 4 Radicals Introduction Detection and Characterization of Radicals Structure and Bonding of Radicals Generation of Free Radicals Stability of Radicals Reactions of Free Radicals Stereochemistry of Radical Reactions Biradicals Summary 5 Carbenes Structure and Geometry of Carbenes Generation of Carbenes Reactions of Carbenes Carbenes and Carbene Ligands in Organometallic Chemistry Summary 6 Niternes ntroduction Structure and Reactivity Generation of Nitrenes Reactions of Nitrenes Summary 7 Miscellaneous intermediates Arynes Ketenes and Cumulenes ortho-Quinone Methides Zwitterions and Dipoles Antiaromatic Systems Tetrahedral Intermediates Summary Index

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Item type	Current library	Call number	Status	Date due	Barcode	Item holds
General Books	Central Library, Sikkim University General Book Section	547.2 SIN/R (Browse shelf(Opens below))	Available		P41387

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Preface

1 Introduction

Reaction Mechanism and Reaction Arrows

Properties and Characteristics of a Reaction

Summary

2 Carbocations

Introduction

History

Sturctures and Geometry of Carbocations

Generation of Carbocation

Carbocation Stability

Detection of Carbocations

Fate of Carbocations

Nonclassical Carbocations

Radical Cations Summary

3 carbanions

Structure and Geometry of Carbanions

Generation of Carbanions

Stability of Carbanions

Reactions of Carbanions

Enolate Reactions with Carbonyl Groups

Rearrangements of Carbanions

Chiral Carbanions

Carbanions and Tautomerism Summary

4 Radicals

Introduction

Detection and Characterization of Radicals

Structure and Bonding of Radicals

Generation of Free Radicals

Stability of Radicals

Reactions of Free Radicals

Stereochemistry of Radical Reactions

Biradicals Summary

5 Carbenes

Structure and Geometry of Carbenes

Generation of Carbenes

Reactions of Carbenes

Carbenes and Carbene Ligands in Organometallic Chemistry

Summary

6 Niternes

ntroduction

Structure and Reactivity

Generation of Nitrenes

Reactions of Nitrenes

Summary

7 Miscellaneous intermediates

Arynes

Ketenes and Cumulenes

ortho-Quinone Methides

Zwitterions and Dipoles

Antiaromatic Systems

Tetrahedral Intermediates

Summary

Index

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