Spectrometric Identification of Organic Compounds/ Robert M. Silverstein, Francis X. Webster, David J. Kiemle, David L. Bryce

Chapter 1 Mass Spectrometry ;
1.1 Introduction ;
1.2 Instrumentation ;
1.3 Ionization Methods ;
1.3.1 Gas-Phase Ionization Methods ;
1.3.1.1 Electron Impact Ionization ;
1.3.1.2 Chemical Ionization ;
1.3.2 Desorption Ionization Methods.
1.3.2.1 Field Desorption Ionization
1.3.2.2 Fast Atom Bombardment Ionization ;
1.3.2.3 Plasma Desorption Ionization ;
1.3.2.4 Laser Desorption Ionization ;
1.3.3 Evaporative Ionization Methods ;
1.3.3.1 Thermospray Mass Spectrometry ;
1.3.3.2 Electrospray Mass Spectrometry.
1.4 Mass Analyzers
1.4.1 Magnetic Sector Mass Spectrometers ;
1.4.2 Quadrupole Mass Spectrometers ;
1.4.3 Ion Trap Mass Spectrometer ;
1.4.4 Time-of-Flight Mass Spectrometer ;
1.4.5 Fourier Transform Mass Spectrometer ;
1.4.6 Tandem Mass Spectrometry.
1.5 Interpretation of EI Mass Spectra
1.5.1 Recognition of the Molecular Ion Peak ;
1.5.2 Determination of a Molecular Formula ;
1.5.2.1 Unit-Mass Molecular Ion and Isotope Peaks ;
1.5.2.2 High-Resolution Molecular Ion ;
1.5.3 Use of the Molecular Formula.
Index of Hydrogen Deficiency.
1.5.4 Fragmentation
1.5.5 Rearrangements ;
1.6 Mass Spectra of Some Chemical Classes ;
1.6.1 Hydrocarbons ;
1.6.1.1 Saturated Hydrocarbons ;
1.6.1.2 Alkenes (Olefins) ;
1.6.1.3 Aromatic and Aralkyl Hydrocarbons ;
1.6.2 Hydroxy Compounds ;
1.6.2.1 Alcohols ;
1.6.2.2 Phenols.