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Organic Chemistry/ Clayden,Jonathan

Material type: Text

TextPublication details: New York: Oxford University press, 2001Edition: 1st.edDescription: 1-1512pISBN: 9780198503460DDC classification: 547

Contents:

Note continued: 39. Determining reaction mechanisms -- There are mechanisms and there are mechanisms -- Determining reaction mechanisms: the Cannizzaro reaction -- Be sure of the structure of the product -- Systematic structural variation -- The Hammett relationship -- Other kinetic evidence for reaction mechanisms -- Acid and base catalysis -- The detection of intermediates -- Stereochemistry and mechanism -- Summary of methods for the investigation of mechanism -- Further reading -- 40. Organometallic chemistry -- Transition metals extend the range of organic reactions -- The 18 electron rule -- Bonding and reactions in transition metal complexes -- Palladium is the most widely used metal in homogeneous catalysis -- The Heck reaction couples together an organic halide or triflate and an alkene -- Cross-coupling of organometallics and halides -- Allylic electrophiles are activated by palladium(O) -- Palladium-catalysed amination of aromatic rings -- Alkenes coordinated to palladium(II) are attacked by nucleophiles -- Palladium catalysis in the total synthesis of a natural alkaloid -- An overview of some other transition metals -- Further reading -- 41. Asymmetric synthesis -- Nature is asymmetric -- The chiral pool: Nature's chiral centres `off the shelf' -- Resolution can be used to separate enantiomers -- Chiral auxiliaries -- Chiral reagents -- Asymmetric catalysis -- Asymmetric formation of carbon-carbon bonds -- Asymmetric aldol reactions -- Enzymes as catalysts -- Further reading -- 42. Organic chemistry of life -- Primary metabolism -- Life begins with nucleic acids -- Proteins are made of amino acids -- Sugars -- just energy sources? -- Lipids -- Mechanisms in biological chemistry -- Natural products -- Fatty acids and other polyketides are made from acetyl CoA -- Terpenes are volatile constituents of plants -- Further reading -- 43. Organic chemistry today -- Science advances through interaction between disciplines -- Chemistry vs viruses -- The future of organic chemistry -- Further reading.

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Holdings
Item type	Current library	Call number	Status	Date due	Barcode	Item holds
General Books Science Library	Science Library, Sikkim University Science Library General Section	547 CLA / (Browse shelf(Opens below))	Available		P08698

Total holds: 0

Note continued: 39. Determining reaction mechanisms --
There are mechanisms and there are mechanisms --
Determining reaction mechanisms: the Cannizzaro reaction --
Be sure of the structure of the product --
Systematic structural variation --
The Hammett relationship --
Other kinetic evidence for reaction mechanisms --
Acid and base catalysis --
The detection of intermediates --
Stereochemistry and mechanism --
Summary of methods for the investigation of mechanism --
Further reading --
40. Organometallic chemistry --
Transition metals extend the range of organic reactions --
The 18 electron rule --
Bonding and reactions in transition metal complexes --
Palladium is the most widely used metal in homogeneous catalysis --
The Heck reaction couples together an organic halide or triflate and an alkene --
Cross-coupling of organometallics and halides --
Allylic electrophiles are activated by palladium(O) --
Palladium-catalysed amination of aromatic rings --
Alkenes coordinated to palladium(II) are attacked by nucleophiles --
Palladium catalysis in the total synthesis of a natural alkaloid --
An overview of some other transition metals --
Further reading --
41. Asymmetric synthesis --
Nature is asymmetric --
The chiral pool: Nature's chiral centres `off the shelf' --
Resolution can be used to separate enantiomers --
Chiral auxiliaries --
Chiral reagents --
Asymmetric catalysis --
Asymmetric formation of carbon-carbon bonds --
Asymmetric aldol reactions --
Enzymes as catalysts --
Further reading --
42. Organic chemistry of life --
Primary metabolism --
Life begins with nucleic acids --
Proteins are made of amino acids --
Sugars --
just energy sources? --
Lipids --
Mechanisms in biological chemistry --
Natural products --
Fatty acids and other polyketides are made from acetyl CoA --
Terpenes are volatile constituents of plants --
Further reading --
43. Organic chemistry today --
Science advances through interaction between disciplines --
Chemistry vs viruses --
The future of organic chemistry --
Further reading.

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