Advances in heterocyclic chemistry. V. 62/ Katritzky, Alan R.

Material type: TextTextPublication details: Academic Press, 1995Description: 418 pISBN: 0120207621DDC classification: 547.59
Contents:
N-Fluoropyridinium salts I Introduction II Synthesis III General properties and spectra IV Reactivity V Future perspectives References New developments in the Chemistry of pyrans I Introduction II Nomenclature III Synthesis from Acyclic precursors IV Synthesis from cyclic precursors V Reactions VI Physical properties and theoretical Chemistry VII Other properties References The Chemistry of Dithiadiazolylium and Dithiadiazolyl rings I Introduction: Dithiadiazolyls, new members of an old class of free radicals II Synthetic approaches to the 1,2,3,5-Dithiadiazolylium cation III Theoretical studies of 1,2,3,5-Dithiadiazolylium Heterocycles IV Physical properties of mono-1,2,3,5-Dithiadiazolylium salts V X-rays diffraction studies of mono-1,2,3,5-Dithiadiazolylium salts VI Reactions of 1,2,3,5-Dithiadiazolylium salts VII Preparation of 1,2,3,5-Dithiadiazolyls VIII Theoretical studies of 1,2,3,5-Dithiadiazolyl radicals IX Physical properties of 1,2,3,5-Dithiadiazolyl radicals X Electron and x-ray diffraction studies of 1,2,3,5-Dithiadiazolyl radicals XI Reactivity of 1,2,3,5-Dithiadiazolyls radicals XII Preparation of Mono-1,3,2,4-Dithiadiazolylium salts XIII Theoretical studies of 1,3,2,4-Dithiadiazolylium salts XIV Physical properties of 1,3,2,4-Dithiadiazolylium salts XV X-ray diffraction studies of 1,3,2,4-Dithiadiazolylium salts XVI Reactivity of 1,3,2,4-Dithiadiazolylium salts XVII Preparation of 1,3,2,4-Dithiadiazolyls XVIII Physical properties of 1,3,2,4-Dithiadiazolyls XIX Theoretical studies of 1,3,2,4-Dithiadiazolyl radicals XX X-ray diffraction studies of 1,3,2,4-Dithiadiazolyls XXI Reactivity of 1,3,2,4-Dithiadiazolyls XXII Multi-1,2,3,5-Dithiadiazolylium salts and Dithiadiazolyls XXIII Multi-1,3,2,4-Dithiadiazolylium salts and dithiadiazolyls XXIV Mixed 1,3,2,4-/1,2,3,5-Dithiadiazolylium salts and related free radicals XXV Conclusions References The reactivity of Tetrathia- and Tetraselenafulvalenes I Introduction and scope II Reactivity of Tetrathiafulvalenes III Reactivity of Tetraselenafulvalenes References Organometallics in coupling reactions in deficient Azaheterocycles I Introduction II Cross-coupling by Hydrogen substitution III Cross-coupling by metal substitution IV Homo-coupling References
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N-Fluoropyridinium salts
I Introduction
II Synthesis
III General properties and spectra
IV Reactivity
V Future perspectives
References

New developments in the Chemistry of pyrans
I Introduction
II Nomenclature
III Synthesis from Acyclic precursors
IV Synthesis from cyclic precursors
V Reactions
VI Physical properties and theoretical Chemistry
VII Other properties
References

The Chemistry of Dithiadiazolylium and Dithiadiazolyl rings
I Introduction: Dithiadiazolyls, new members of an old class of free radicals
II Synthetic approaches to the 1,2,3,5-Dithiadiazolylium cation
III Theoretical studies of 1,2,3,5-Dithiadiazolylium Heterocycles
IV Physical properties of mono-1,2,3,5-Dithiadiazolylium salts
V X-rays diffraction studies of mono-1,2,3,5-Dithiadiazolylium salts
VI Reactions of 1,2,3,5-Dithiadiazolylium salts
VII Preparation of 1,2,3,5-Dithiadiazolyls
VIII Theoretical studies of 1,2,3,5-Dithiadiazolyl radicals
IX Physical properties of 1,2,3,5-Dithiadiazolyl radicals
X Electron and x-ray diffraction studies of 1,2,3,5-Dithiadiazolyl radicals
XI Reactivity of 1,2,3,5-Dithiadiazolyls radicals
XII Preparation of Mono-1,3,2,4-Dithiadiazolylium salts
XIII Theoretical studies of 1,3,2,4-Dithiadiazolylium salts
XIV Physical properties of 1,3,2,4-Dithiadiazolylium salts
XV X-ray diffraction studies of 1,3,2,4-Dithiadiazolylium salts
XVI Reactivity of 1,3,2,4-Dithiadiazolylium salts
XVII Preparation of 1,3,2,4-Dithiadiazolyls
XVIII Physical properties of 1,3,2,4-Dithiadiazolyls
XIX Theoretical studies of 1,3,2,4-Dithiadiazolyl radicals
XX X-ray diffraction studies of 1,3,2,4-Dithiadiazolyls
XXI Reactivity of 1,3,2,4-Dithiadiazolyls
XXII Multi-1,2,3,5-Dithiadiazolylium salts and Dithiadiazolyls
XXIII Multi-1,3,2,4-Dithiadiazolylium salts and dithiadiazolyls
XXIV Mixed 1,3,2,4-/1,2,3,5-Dithiadiazolylium salts and related free radicals
XXV Conclusions
References

The reactivity of Tetrathia- and Tetraselenafulvalenes
I Introduction and scope
II Reactivity of Tetrathiafulvalenes
III Reactivity of Tetraselenafulvalenes
References

Organometallics in coupling reactions in deficient Azaheterocycles
I Introduction
II Cross-coupling by Hydrogen substitution
III Cross-coupling by metal substitution
IV Homo-coupling
References

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