Organic chemistry/ (Record no. 176512)

MARC details
000 -LEADER
fixed length control field 07782nam a2200157Ia 4500
020 ## - INTERNATIONAL STANDARD BOOK NUMBER
International Standard Book Number 9788126514434
040 ## - CATALOGING SOURCE
Transcribing agency CUS
082 ## - DEWEY DECIMAL CLASSIFICATION NUMBER
Classification number 547
Item number SOL/O
100 ## - MAIN ENTRY--PERSONAL NAME
Personal name Solomons,T.W. Graham
245 #0 - TITLE STATEMENT
Title Organic chemistry/
Statement of responsibility, etc. T.W. Graham Solomons
250 ## - EDITION STATEMENT
Edition statement 9th.ed.
260 ## - PUBLICATION, DISTRIBUTION, ETC. (IMPRINT)
Place of publication, distribution, etc. New Delhi:
Name of publisher, distributor, etc. Wiley India,
Date of publication, distribution, etc. 2008.
300 ## - PHYSICAL DESCRIPTION
Extent 1244p.
505 ## - FORMATTED CONTENTS NOTE
Formatted contents note <br/>BONDING AND MOLECULAR STRUCTURE:The Basics l<br/>Molecular Graphic: Glycine, an organic molecule found :n space 1<br/>1.1 Organic Chemistry and Life 2<br/>1.2 The Structural Theory of Organic Chemistry 3<br/>1.3 Isomers: The Importance of Structural Formulas 4<br/>1.4 Chemical Bonds: The Octet Rule 5<br/>1.5 Wr.ting Lewis Structures 7<br/>1.6 Exceptions to the Octet Rule 9<br/>1.7 Formal Charge 10<br/>1.8 Resonance Theory 13<br/>1.9 Quantum Mechanics and Atomic Structure 18<br/>1.10 Atomic Orbitals and Electron Configuration 20<br/>1.11 Molecular Orbitals 21<br/>1.12 The Structure of Methane and Ethane:sp^ Hybridization 24<br/>THE CHEMISTRY OF... Calculated Molecular Models: Electron Density Surfaces 28<br/>1.13 The Structure ofEthene(Ethylene):sp^ Hybridization 28<br/>1.14 The Structure of Ethyne(Acetylene):sp Hybridization 33<br/>1.15 A Summary of important Concepts that Come from Quantum Mechanics 35<br/>1.16 Molecular Geometry: The Valence Shell Electron Pair Repulsion Model 36<br/>1.17 Representation of Structural Formulas 39<br/>1.18 Applications of Basic Principles 44<br/>FUNCTIONAL GROUPS,INTERMOLECULAR FORCES,AND<br/>INFRARED(IR)SPECTROSCOPY 51<br/>Structure and Function: Organic Chemistry, Nanotechnology,and Bioengineering/<br/>Molecular Graphic: A molecular template for bone growth 51<br/>2.1 Carbon-Carbon Covalent Bonds 52<br/>2.2 Hydrocarbons: Representative Alkanes, Alkenes, Alkynes,and Aromatic<br/>Compounds 52<br/>2.3 Polar Covalent Bonds55<br/>THE CHEMISTRY OF...Calculated Molecular Models: Maps of Electrostatic Potential<br/>2.4 Polar and Nonpolar Molecules 56<br/>Functional Groups 59<br/>AlkyI Halides or Haloalkanes 60<br/>Alcohols 61<br/>Ethers 63<br/>Amines 63<br/>Aldehydes and Ketones 65<br/>Carboxylic Acids, Esters,and Amides 65<br/>Nitrites 67<br/>Summary of important Families organic Compounds 68<br/>Physical Properties and Molecular Structure 68<br/>Summary of attractive Electric Forces 75<br/>the CHEMISTRY OF...Organic Templates Engineered to Mimic Bone Growth 75<br/>2.16 Infrared Spectroscopy:An Instrumental Method for Detecting Functional Groups<br/>2.17 Applications of basic Principles 84<br/>ACIDS AND BASES:An Introduction to<br/>Organic Reactions and Their Mechanisms 91<br/>Shuttling of Protons/Molecular Graphic: Diamox, a drug that prevents altitude<br/>sickness 91<br/>3.1 Reactions and Their Mechanisms 92<br/>3.2 Acid-Base Reactions 94<br/>THE CHEMISTRY OF...HOMOsand LUMOs in Reactions 97<br/><br/>3.3 Hcterolysis of Bondfi to C.irhnn Cofb<Ho!: .ttid C.irixtmofi'. 97<br/>3.4 The Uio of Curved Arrows <br/>3.5 The Strength of acids a<br/>3.6 Predicting the Outcome of Acid-Base Reactions 103<br/>3.7 The Relationship between Sinjcturo and Ac-dry 105<br/>3.8 Energy Changes 108<br/>3.9 The Relationship between the ('equilibrium Constant <br/>Change.SG" 110<br/>3.10 The Acidity of Carboxylic Acids 111<br/>3.11 The Effect of the Solvent on Aadity 115<br/>3.12 Organic Compounds as Bases 116<br/>3.13 A Mechanism for an Organic Reaction 117<br/>THE CHEMISTRY OF . Carbonic Anhydrase 118<br/>3.14 Acids and Bases m Nonaqueous Solutions 119<br/>3.15 Acid-Base Reactions and the Synthesis of Deuterium- and<br/>Tritium-Labeled Compounds 120<br/>3.16 Applications of Basic Principles 121<br/>NOMENCLATURE AND CONFORMATIONS<br/>OF ALKANES 129<br/>7b Be Flexible or Inflexible - Molecular Structure Makes the Difference/ Molecular<br/>Graphic: A portion of the structure of diamond,an exceptionally rigid molecule 129<br/>4.1 Introduction to Alkanes and Cycloalkanes 130<br/>^ THE CHEMISTRY OF... Petroleum Refining 130<br/>4.2 Shapes ofAlkanes 132<br/>4.3 IUPAC Nomenclature of alkanes. AlkyI Hades. and Alcohols 134<br/>4.4 Nomenclature ofCycloalkanes 141<br/>4.5 Nomenclature of Alkenes and Cycloalkenes 143<br/>4.6 Nomenclature ofAlkynes 145<br/>4.7 Physical Properties of alkanes and Cycloalkanes 146<br/>'THE CHEMISTRY OF... Pheromones:Communication by Means of Chemicals 148<br/>4.8 Sigma Bonds and Bond Rotation 148<br/>4.9 Conformational Analysis of Butane 151<br/>4.10 The Relative Stabilities ofCycloalkanes: Ring Strain 153<br/>4.11 The Origin offering Strain in Cyclopropane and Cyclobutane:<br/>Angle Strain and Torsional Strain 155<br/>4.12 Conformations ofCyclohexane 156<br/>THE CHEMISTRY OF... Nanoscale Motors and Molecular Switches 159<br/>4.13 Substituted Cyclohexanes:Axial and Equatorial Hydrogen Atoms 160<br/>4.14 Disubstituted Cycloalkanes: Cis-Trans Isomerism 163<br/>4.15 Bicyclic and Polycyclic Alkanes 166<br/>THE CHEMISTRY OF...Elemental Carbon 167<br/>4.16 Chemical Reactions of alkanes 168<br/>4.17 Synthesis of alkanes and Cycloalkanes 168<br/>4.18 Structural Information from Molecular Formulas and the Index of<br/>Hydrogen Deficiency 169<br/>4.19 NMR Spectroscopy-A Practical Introduction 171<br/>4.20 Applications of basic Principles 175<br/>STEREOCHEMISTRY:Enantiomers and Diastereomers 181<br/>The Handedness ofLife/Molecular Graphic: The mirror-image stereoisomers of<br/>alanine,a chiral amino acid 181<br/>5.1 The Biological Significance ofChirality 182<br/>5.2 Isomerism: Constitutional Isomers and Stereoisomers 183<br/>5.3 Enantiomers and Chiral Molecules 184<br/>5.4 More about the Biological Importance ofChirality 187<br/>5.5 Historical Origin ofStereochemistry 1885.6 Tests for Chirality: Planes of Symmetry 189<br/>5.7 Nomenclature of Enantiomers: The R.S-Syslcm 190<br/>5.8 Properties of enantiomers: Optical Activity 194<br/>5.9 The Origin of Optical Activity 198<br/>5.10 The Synthesis of Chiral Molecules 200<br/>5.11 Chiral Drugs 202<br/>THE CHEMISTRY OF ... Selective Binding of Drug Enantiomers to Left- and<br/>Rig fit-Handed Coiled DNA 203<br/>5.12 Molecules With More than One Chirality Center 203<br/>5.13 Fischer Projection Formulas 207<br/>5.14 Stereoisomerism of Cyclic Compounds 209<br/>5.15 Relating Configurations through Reactions in WIvch No Bonds to<br/>the Chirality Center Are Broken 211<br/>5.16 Separation of Enantiomers: Resolution 213<br/>5.17 Compounds with Chirality Centers Other than Carbon 214<br/>5.18 Chiral Molecules that Do Not Possess a Chirality Center 215<br/>i:<br/>REACTIONS OF ALKYL HALIDES:<br/>Nucleophilic Substitution and Elimination 221<br/>Breaking Bacterial Cell Walls with Organic Chemistry/ Molecular Graphic: Lysozyme 221<br/>6.1 Organic Halides 222<br/>6.2 Nucleophilic Substitution Reactions 224<br/>6.3 Nucleophiles 224<br/>6.4 Leaving Groups 225<br/>6.5 Kinetics of a Nucleophilic Substitution Reaction: An Sf^2 Reaction 226<br/>6.6 A Mechanism for the Sn2 Reaction 227<br/>6.7 Transition State Theory: Free-Energy Diagrams 228<br/>6.8 The Stereochemistry of Si\i2 Reactions 231<br/>THE CHEMISTRY OF...Lysozyme 234<br/>6.9 The Reaction after-Butyl Chloride with Hydroxide Ion:An Si^l Reaction 235<br/>6.10 A Mechanism for the S^l Reaction 236<br/>6.11 Carbocations 237<br/>6.12 The Stereochemistry of SnI Reactions 239<br/>6.13 Factors Affecting the Rates ofS^l and Sf^2 Reactions 241<br/>. 6.14 Organic Synthesis: Functional Group Transformations Using Sn2 Reactions 250<br/>^ THE CHEMISTRY OF...Biological Methylation:A Biological nucleophilic substitution<br/>Reaction 251<br/>6.15 Elimination Reactions ofAlky!Halides 253<br/>6.16 The E2Reaction 255<br/>6.17 The El Reaction 256<br/>6.18 Substitution versus Elimination 257<br/>6.19 Overall Summary 260<br/>ALKENES AND ALKYNES-Part I:<br/>Elimination Reactions of AlkyI Halides 269<br/>Cell Membrane Fluidity/Molecular Graphic: cis-9-Octadecenoic acid, and unsaturated<br/>fatty acid incorporated into cell membrane phospholipids 269<br/>7.1 Introduction 270<br/>7.2 The(EHZ)System for Designating Alkene Diastereomers 270<br/>7.3 Relative Stabilities ofAlkenes 272<br/>7.4 Cycloalkenes 274<br/>7.5 Synthesis ofAlkenes via Elimination Reactions 274<br/>7.6 Dehydrohalogenation ofAlkyI Halides 275<br/>7.7 Acid-Catalyzed Dehydration of Alcohols 280<br/>7.8 Carbocation Stability and the Occurrence ofMolecular Rearrangements 285<br/>7.9 Synthesis ofAlkynes by Elimination Reactions 2887.10 The Acidity of Torm-nal Alkynrs 290<br/>
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        Science Library, Sikkim University Science Library, Sikkim University Science Library General Section 29/08/2016 547 SOL/O P31512 14/02/2024 13/02/2024 General Books Science Library Books For SU Science Library
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