Electron paramagnetic Resonance Spectroscopy Fundamentals

Bertrand,Patrick

Electron paramagnetic Resonance Spectroscopy Fundamentals - France: Springer, 2021. - 422p.

The electron paramagnetic resonance phenomenon --
Chapter 2 --
Hyperfine structure of a spectrum in the isotropic regime --
Chapter 3 --
Introduction to the formalism of the space of spin states. The Hamiltonian operator --
Chapter 4 --
How anisotropy of the g and A matrices affects spectrum shape for radicals and transition ion complexes --
Chapter 5 --
Spectrum intensity, saturation, spin-lattice relaxation --
Chapter 6 --
The zero-field splitting term. EPR spectrum for paramagnetic centres of spin greater than 1/2 --
Chapter 7 --
Effects of dipolar and exchange interactions on the EPR spectrum. Biradicals and polynuclear complexes --
Chapter 8 --
EPR spectrum for complexes of rare earth and actinide ions --
Chapter 9 --
How instrumental parameters affect the shape and intensity of the spectrum. Introduction to simulation methods --
Appendix 1 --
Expression of the magnetic moment of a free atom or ion --
Appendix 2 --
Expression of g and A matrices given by ligand field theory for a transition ion complex --
Appendix 3 --
Dipolar interactions between a nuclear magnetic moment and electron spin magnetic moments --
Appendix 4 --
Some properties of angular momentum operators. Spin coupling coefficients and equivalent operators. Application to Landé's formula and to dipolar hyperfine interactions. --
Appendix 5 --
The notion of spin density --
Appendix 6 --
Example of calculation of the spin-lattice relaxation time T_1: the direct process? --
Appendix 7 --
Matrix elements of operators defined from components of an angular momentum

9783030396657


Spectroscopy and Microscopy.
Magnetism, Magnetic Materials.

543.67 / BER/E
SIKKIM UNIVERSITY
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