Organic Chemistry/
Organic Chemistry/
Clayden,Jonathan
- 1st.ed.
- New York: Oxford University press, 2001.
- 1-1512p.
Note continued: 39. Determining reaction mechanisms --
There are mechanisms and there are mechanisms --
Determining reaction mechanisms: the Cannizzaro reaction --
Be sure of the structure of the product --
Systematic structural variation --
The Hammett relationship --
Other kinetic evidence for reaction mechanisms --
Acid and base catalysis --
The detection of intermediates --
Stereochemistry and mechanism --
Summary of methods for the investigation of mechanism --
Further reading --
40. Organometallic chemistry --
Transition metals extend the range of organic reactions --
The 18 electron rule --
Bonding and reactions in transition metal complexes --
Palladium is the most widely used metal in homogeneous catalysis --
The Heck reaction couples together an organic halide or triflate and an alkene --
Cross-coupling of organometallics and halides --
Allylic electrophiles are activated by palladium(O) --
Palladium-catalysed amination of aromatic rings --
Alkenes coordinated to palladium(II) are attacked by nucleophiles --
Palladium catalysis in the total synthesis of a natural alkaloid --
An overview of some other transition metals --
Further reading --
41. Asymmetric synthesis --
Nature is asymmetric --
The chiral pool: Nature's chiral centres `off the shelf' --
Resolution can be used to separate enantiomers --
Chiral auxiliaries --
Chiral reagents --
Asymmetric catalysis --
Asymmetric formation of carbon-carbon bonds --
Asymmetric aldol reactions --
Enzymes as catalysts --
Further reading --
42. Organic chemistry of life --
Primary metabolism --
Life begins with nucleic acids --
Proteins are made of amino acids --
Sugars --
just energy sources? --
Lipids --
Mechanisms in biological chemistry --
Natural products --
Fatty acids and other polyketides are made from acetyl CoA --
Terpenes are volatile constituents of plants --
Further reading --
43. Organic chemistry today --
Science advances through interaction between disciplines --
Chemistry vs viruses --
The future of organic chemistry --
Further reading.
9780198503460
547 / CLA /
Note continued: 39. Determining reaction mechanisms --
There are mechanisms and there are mechanisms --
Determining reaction mechanisms: the Cannizzaro reaction --
Be sure of the structure of the product --
Systematic structural variation --
The Hammett relationship --
Other kinetic evidence for reaction mechanisms --
Acid and base catalysis --
The detection of intermediates --
Stereochemistry and mechanism --
Summary of methods for the investigation of mechanism --
Further reading --
40. Organometallic chemistry --
Transition metals extend the range of organic reactions --
The 18 electron rule --
Bonding and reactions in transition metal complexes --
Palladium is the most widely used metal in homogeneous catalysis --
The Heck reaction couples together an organic halide or triflate and an alkene --
Cross-coupling of organometallics and halides --
Allylic electrophiles are activated by palladium(O) --
Palladium-catalysed amination of aromatic rings --
Alkenes coordinated to palladium(II) are attacked by nucleophiles --
Palladium catalysis in the total synthesis of a natural alkaloid --
An overview of some other transition metals --
Further reading --
41. Asymmetric synthesis --
Nature is asymmetric --
The chiral pool: Nature's chiral centres `off the shelf' --
Resolution can be used to separate enantiomers --
Chiral auxiliaries --
Chiral reagents --
Asymmetric catalysis --
Asymmetric formation of carbon-carbon bonds --
Asymmetric aldol reactions --
Enzymes as catalysts --
Further reading --
42. Organic chemistry of life --
Primary metabolism --
Life begins with nucleic acids --
Proteins are made of amino acids --
Sugars --
just energy sources? --
Lipids --
Mechanisms in biological chemistry --
Natural products --
Fatty acids and other polyketides are made from acetyl CoA --
Terpenes are volatile constituents of plants --
Further reading --
43. Organic chemistry today --
Science advances through interaction between disciplines --
Chemistry vs viruses --
The future of organic chemistry --
Further reading.
9780198503460
547 / CLA /